abc® Aalco is a registered trademark of Aalco Metals Ltd
© Copyright: Aalco Metals Ltd, The Hersham Centre, Hersham Green, Hersham, Surrey KT12 4HP
All Data is indicative only and must not be seen as a substitute for the full specification from which it is drawn.
In particular, the mechanical property requirements vary widely with product form and product dimensions.
For more complete details please refer to the relevant specification – The BS EN Specifications for Stainless Steel
are listed on a separate Datasheet.
Duplex Stainless Steel
Duplex stainless steels are extremely
corrosion resistant, work hardenable
alloys. Their microstructures consist of
a mixture of austenite and ferrite
phases. As a result, duplex stainless
steels display properties characteristic
of both austenitic and ferritic stainless
steels. This combination of properties
can mean some compromise when
compared with pure austenitic and
pure ferritic grades.
Duplex stainless steels are in most
cases, tougher than ferritic stainless
steels. Strengths of duplex stainless
steels can in some cases be double that
for austenitic stainless steels.
Whilst duplex stainless steels are
considered resistant to stress corrosion
cracking, they are not as resistant to
this form of attack as ferritic stainless
steels. However, the corrosion
resistance of the least resistant duplex
stainless steels is greater than that for
the most commonly used grades of
stainless steels, i.e. 304 and 316.
Duplex steels are also magnetic, a
property that can be used to easily
differentiate them from common
austenitic grades of stainless.
Property data given in this document is
typical for flat rolled products covered
by ASTM A240/A240M. ASTM, EN or
other standards may cover products
sold by Aalco. It is reasonable to
expect specifications in these
standards to be similar but not
necessarily identical to those given in
this datasheet.
Applications
Duplex stainless steels are typically used
in:
Chemical processing, transport and
storage
Oil and gas exploration and offshore rigs
Oil and gas refining
Marine environments
Pollution control equipment
Pulp & paper manufacturing
Chemical process plant
Alloy Designations
Due to excellent corrosion resistance and
high strength, one of the most widely used
duplex stainless steel in recent years has
been 1.4462, also known as 2205. The
name 2205 comes from a typical
composition of 22% Chromium and 5%
Nickel. There are many other duplex
stainless steels such as 1.4507, 1.4410 &
1.4362 as well as proprietary grades
developed by individual manufacturers such
as LDX2101 from Outokumpu. Recently
there has been a resurgence of interest in
these ‘lean’ duplex grades as the high price
of Nickel/Molybdenum means they can be
price-competitive with austenitic grades.
Euronorm UNS BS Grade
1.4462 S31803
S32205
318S13 2205
1.4507 S32520
S32550
- -
LDX2101
Typical Chemical Compositions
% 1.4462 1.4507 1.4410
LDX
2101
C 0.03
max
0.03
max
0.03
max
0.03
max
Mn 2.0 1.5 1.5 5.0
Si 1.0 0.8
P 0.03 0.035
S 0.02 0.02
Cr 21-23 24-26 24-26 21.5
Mo 2.5-3.5 3.0-5.0 3.0 0.3
Ni 4.5-6.5 5.5-8.0 6 1.5
N 0.08-
0.2
0.2-
0.35
0.2
0.22
Cu - 0.5-3.0 0.5-3.0
abc® Aalco is a registered trademark of Aalco Metals Ltd
© Copyright: Aalco Metals Ltd, The Hersham Centre, Hersham Green, Hersham, Surrey KT12 4HP
All Data is indicative only and must not be seen as a substitute for the full specification from which it is drawn.
In particular, the mechanical property requirements vary widely with product form and product dimensions.
For more complete details please refer to the relevant specification – The BS EN Specifications for Stainless Steel
are listed on a separate Datasheet.
Typical Mechanical Properties
Grade 1.4462 1.4507 2101
Tensile
Strength (MPa)
620 770
675
Proof Stress
0.2% (MPa)
450 550
500
Elongation A5
(%)
25 25
30
Hardness
Rockwell C
31 -
Typical Physical Properties
Property 2205 1.4507
Density (g.cm3) 7.805 7.810
Modulus of
Elasticity (GPa)
200 205
Electrical
Resistivity
(Ω.m)
0.085x10-6 0.085x10-6
Thermal
Conductivity
(W/m.K)
19 at 100°C 17 at
100°C
Thermal
Expansion
(m/m.K)
13.7x10-6
to 100°C
13.5x10-6
to 200°C
Corrosion Resistance
Duplex stainless steels are extremely
corrosion resistant. They have high
resistance to intergranular corrosion. Even
in chloride and sulphide environments,
duplex stainless steels exhibit very high
resistance to stress corrosion cracking.
The super duplex grades are even more
resistant to corrosion.
Heat Resistance
The high chromium content of duplex
stainless steels that protects against
corrosion, causes embrittlement at
temperatures over about 300°C.
At low temperatures duplex stainless steels
have better ductility than the ferritic and
martensitic grades. Duplex grades can
readily be used down to at least -50°C.
Fabrication
Fabrication of all stainless steels should be
done only with tools dedicated to stainless
steel materials. Tooling and work surfaces
must be thoroughly cleaned before use.
These precautions are necessary to avoid
cross contamination of stainless steel by
easily corroded metals that may discolour
the surface of the fabricated product.
Heat Treatment
Duplex stainless steels cannot be hardened
by heat treatment. They can however be
work hardened.
Solution treatment or annealing can be
done by rapid cooling after heating to
around 1100°C.
Machinability
Although machinable, the high strengths of
duplex stainless steels makes machining
difficult. As an example, machining of 2205
is around 20% slower than for 304.
Machining can be enhanced by using the
following rules:
Cutting edges must be kept sharp. Dull
edges cause excess work hardening.
Cuts should be light but deep enough to
prevent work hardening by riding on the
surface of the material.
Chip breakers should be employed to
assist in ensuring swarf remains clear of
the work
Low thermal conductivity of austenitic
alloys results in heat concentrating at
the cutting edges. This means coolants
and lubricants are necessary and must
be used in large quantities.
abc® Aalco is a registered trademark of Aalco Metals Ltd
© Copyright: Aalco Metals Ltd, The Hersham Centre, Hersham Green, Hersham, Surrey KT12 4HP
All Data is indicative only and must not be seen as a substitute for the full specification from which it is drawn.
In particular, the mechanical property requirements vary widely with product form and product dimensions.
For more complete details please refer to the relevant specification – The BS EN Specifications for Stainless Steel
are listed on a separate Datasheet.
Welding
Duplex stainless steels have good
weldability. All standard welding processes
can be used. They are not quite as easily
welded as the austenitic grades but low
thermal expansion in duplex grades reduces
distortion and residual stresses after
welding. The recommended filler material
for 2205 stainless steel is 2209.
Supplied Forms
Aalco typically supplies 2205 duplex
stainless steel in the following forms:
Round bar
CCP plate
Quarto plate
This information is based on our present
knowledge and is given in good faith.
However, no liability will be accepted by the
Company is respect of any action taken by
any third party in reliance thereon
As the products detailed may be used for a
wide variety of purposes and as the
Company has no control over their use; the
Company specifically excludes all conditions
or warranties expressed or implied by
statute or otherwise as to dimensions,
properties and/or fitness for any particular
purpose. Any advice given by the Company
to any third party is given for that party’s
assistance only and without liability on the
part of the Company.
Any contract between the Company and a
customer will be subject to the Company’s
Conditions of Sale. The extent of the
Company’s liabilities to any customer is
clearly set out in those Conditions; a copy
of which is available on request.