常用化学试剂英文缩写及其结构式列表

常用化学试剂英文缩写及其结构式列 OOC•O2,7,8-Trioxabicyclo[3.2.1]octyl ABO •CAc OAcetyl O-N+N•CON4-Azidobenzyloxycarbonyl ACBZ ACE α-Chloroethoxycarbonyl CH•2O AcHmb OO2-Acetoxy-4-methoxybenzyl O•H2CNAcm HAcetamidomethyl C•1-Adamantyl Ad OOC• 1-Adamantyloxycarbonyl Adoc OC•O 1-(1-Adamantyl)-1-methylethoxycarbonyl Adpoc NNNNAIBN 2,2’-Azobis(2-methylpropionitrile) or Azobisisobutyronitrile CH•All Allyl 2 •CAlloc OOAlloxycarbonyl O S•Allylsulfonyl OAls OC• OO2-(Acetoxymethyl)benzoyl AMB OCH•4-Methoxyphenyl or anisyl AN •H2C -O+NO Anpe 2-(4-Acetyl-2-nitrophenyl)ethyl O •CAOC OOAllyloxycarbonyl •H2COOp-Anisyloxymrthyl or (4-methoxyphenoxy)methyl p-AOM Aryl 芳香基 Ar Adenosine 5’-triphosphate 三磷酸腺苷 ATP ATPase Adenosinetriphosphatase ATP酶 CH•2-N+NAzb p-Azidobenzyl N O Benzamidomethyl •H2CNHBam BBA Butane-2,3-bisacetal •H2CBrp-Bromobenzyl BBn BH9-Borabicyclo[3.3.1]nonane 9-BBN BDMS Biphenyldimethylsilyl S•HC1,3-Benzodithiolan-2-yl S BDT Bic 5-Benzisoxazolymethoxycarbonyl S OSO2,4-Dimethylthiophenoxycarbonyl C•Bmpc Bmpm 1,1-Bis(4-methoxyphenyl)-1’-pyrenylmethyl BSHBMS Borane-methyl sulfide •H2CBenzyl Bn •COt-Butylcarbonyl BOC •H2CO Benzyloxymethyl BOM Benzotriazol-1-yloxytris(dimethylamino) phosphonium hexafluorophosphate NO+PNNNNNBOP BOP-Cl N,N-Bis(2-oxo-3-oxazolidinyl)phosphinic bp Boiling point Bpoc 1-methyl-1-(4-biphenyl)ethoxycarbonyl N N2,2’-Bipyridyl Bpy SiNOSiBistrimethylsilyl acetamide BSA •NNBenzotriazo-1-yl or 1-benzotriazolyl NBt +N Benzyltributylammonium chloride BTBA •H2CBu Butyl CSec-Butyl •Hs-BU C• tert-Butyl t-Bu OCH•2t-Butoxymethyl Bum OOC•1-(3,5-Di-t-butylphenyl)-1-methylethoxycarbonyl t-Bumeoc O•CBenzoyl Bz Cam Carboxyamidomethyl cAMP Adenosine cyclic 3’,5’-phosphate -O-+ONO+NH4 -O-+-ONOO+NO-+4-OCeO+ON-+-OONO-Cerium(IV) ammonium nitrate OCAN O•COBenzyloxycarbonyl Cbz CD Circular dichrosim O NNNN1,1’-Carbonyldiimidazole CDI H•CClCee O1-(2-Chloroethoxy)ethyl CI Chemical ionization (in MS) Configuration interaction (in MO theory) CIDNP Chemically induced dynamic nuclear polarization cm Centmeter +NClCMPI 2-Chloro-1-methylpyridium chloride CNDO Complete neglect of differential overlap OOCCoc Cinnamyloxycarbonyl • COD 1,5-Cyclooctadiene COSY Correlation spectroscopy COT Cyclooctatetrene C• Cyclopentadienyl Cp CPTr 4,4’,4”-Tris(4,5-dichlorophthalimido)riphenylmethyl OSOHO Camphorsulfonic acid OCSA Cl OC•NCTMP 1-[(2-Chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl OOHHN2Cysteine SHCys δ Chemical shift in ppm d Day NNDABCO 1,4-Diazabicyclo[2.2.2]octane H•CDAM Di(4-methoxyphenyl)methyl OO FFSFN Diethylaminosulfurtrifluoride DAST DB-t-BOC 1,1-Dmethyl-2,2-dibromoethoxycarbonyl DBD-Tmoc 2,7-Di-t-butyl[9-(10,10-dioxo-10,10,10,10-tetrahydrothioxanthyl)methy lcarbonyl DBN 1,5-Diazabicyclo[4.3.0]non-5ene N N1,8-Diazabicyclo[5.4.0]undec-7-ene DBU NCNDicyclohexylcarbodiimide DCC +NHClDichloromethylammonium chloride ClDCMME NO NCl 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone OClDDQ DEAD Diethylazodicarboxylate Si•DEIPS Diethylisopropylsilyl DEPT Distortionless enhancement by polarization transfer DG Diacyl glycerol ONOONODiisopropyl azodicarboxylate DIAD -DIBAH H+AlDiisobutylalumium hydride DIBAL Dim 2-(1,3-Dithianyl)methyl N DiisopropylethylamineDIPEA OOHOODiisopropyl tartrate HOODIPT O NDMAC Dimethylacetamide O OO Diethyl acetylenedicarboxylate ODMAD NN4-Dimethylaminopyridine DMAP ODimethoxyethane ODME ONN,N-Dimethylformamide DMF Si• DMIPS Dimethylisopropylsilyl SSO•CODithianylmethoxycarbonyl Dmoc Dimethylpropane DMP O•HPDimethylphosphinyl Dmp O •H2CODMPM 3,4-Dimethoxybenzyl NON1,3-Dimethyl-3,4,5,6-tetrhydro-2(1H)-pyrimidinone DMPU OOSODimethyl sulfate ODMS OSDimethyl sulfoxide or methyl sulfoxide DMSO C•Dimethoxytrityl OODMT C• Di(p-methoxyphenyl)phenylmethyl OODMTr DNA Deoxyribonucleic acid DNB p,p’-Dinitrobenzhyrryl OS•O O O 4-(4’,8’-Dimethoxynaphthylmethyl)benzenesulfonyl DNMBS CH•--OO++NN2,4-Dinitrophenyl OODNP OC•HOOBp-(Dihydroxyboryl)benzyloxycarbonyl HODobz CDPM Diphenylmethyl •H SiH•2Diphenylmethylsilyl DPMS H•PDiphenylphosphinyl ODpp OOPO+-NNNDiphenylphosphoryl azide DPPA •H2C P 2-(Diphenylphosphino)ethyl Dppe CH•2 N(Diphenyl-4-pyridyl)methyl Dppm OPSS•HDiphenylthiophosphinyl Dpt :SiDi-t-butylsilylene DTBMS SSONODts •Dithiasuccinimidyl E1 Unimolecular elimination E2 Bimolecular elimination ED50 Dose that is effective in 50% of test subjects EDC 1-Ethyl-3-(3’-dimethylaminopropyl)carbodiimide HOOHOONNOO Ethylenediaminetetraacetic acid HOOHEDTA H•CEE O1-Ethoxyethyl ee Enantiomeric excess EI Electron impact (in MS) ESR Electron spin resonance Et Ethyl •H2C FAB Fast atom bombardment (in MS) Fcm-NR2 N-Ferrocenylmethyl FD Field Field distortion (in MS) FG Founctional group FID Flame ionization detection or Free induced decay (in NMR) CH•2 9-Fluorenylmethyl Fm -O ONFMOC 9-Fluorenylmethylcarbamate Fp η5 FT Foutier transform g Gram GC Gas chromatography OHOHOOHOPPOOOPOHO OHOHN2NNOHHN NGTP Guanosine 5’-triphosphate OGUM Guaiacolmethyl h Hour ClClClOClClClHexachloroacetone HCA Hex Hexyl •H2C HMDS 1,11,3,3,3-Hexamethyldisilazane HMO Huckel molecular orbital NOPNNHexamethylphosphoramide HMPA NPNN Hexamethylphosphoroustriamide HMPT NN NHOBT OH1-Hydroxybenzotriazole HOMO Highest occupied molecular orbital HPLC High performance liquid chromatography HRMS High-resolution mass spectrum hν Irradiation with light Hz Hertz hZ Homobenzyloxycarbonyl ICR Ion cyclotron resonance N N OC• 3-(Imidazole-1-ylmethyl)-4’,4”-dimethoxytriphenylmethyl OIDTr •NNImidazole-1-yl or 1-imidazolyl Im OOS•OO2,6—Dimethoxy-4-methylbenzenesulfonyl iMds INDO Incomplete neglect of differential overlap IP Ionization potential C•OO1-Isopropylallyloxycarbonyl Ipaoc Isopr Si• IPDMS opyldimethylsilyl IR Infrared J Coupling constant (in NMR) k Kilo +K-KAPA HNNHPotassium 3-aminopropylamide 2+K-NSiSiKHMDS Potassium bis(trimethylsilyl)amide or potassium hexamrthyldisilane L Triphenylphosphine ligand or liter -H+++-AlH+-LiH- Lithium aluminum hydride HLAH LCAO Linear combination of atomic orbitals -N+LDA Lithium diisopropylamide LiLDBB 4,4’-Di-tert-butyybiphenyl ylide OOCLev Levulinoyl • LevS Levulinoyldithioacetal ester 4,4-(ethylenedithio)pentanoyl LFER Linear free energy relationship -N+LiLithium isopropylcyclohexylamide LICA +Li-NSiSiLHMDS Lithium bis(trimethylsilyl)amide or lithium hexamrthyldisilane -OO O++PbO-O-OO -Lead tetraacetate OLTA LTMP Lithium 2,2,6,6-tetramethylpiperidide LUMO Lowest unoccupied molecular orbital μ Micro m Multiple (spectral), meter, milli M Moles per liter or mega MAD Methylaluminum bis(2,6-di-t-butyl-4-methylphenoxide C•OMBE 1-Methyl-1-benzyloxyethyl OC2,3,3a,4,5,6,7,7a-Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran2-yl H•MBF OS•Op-Methoxybenzenesulfonyl OMBS OOHO m-Chloroperbenzoic acid ClMCPBA OS•O O2,6-Dimethyl-4-methoxybenzenesulfonyl Mds MEM α-Methoxyethoxymethyl O•COO p-Methoxybenzyloxycarbonyl MeOZ CH•Mesityl 2,4,6-trimethylphenyl Mes MHz Megahertz min Minute MINDO Modified intermediate neglect of differential overlap mM Millimoles per liter O C• p-Methoxyphenyldiphenylmethyl MMTr OMOM CH•Methoxymethyl 2MoOPH Oxodiperoxymolybdenum(pyridine) hexamethylphosphoramide O•COOp-Methoxybenzyloxycarbonyl Moz mp Melting point OCH•2p-Methoxyphenylmethyl or p-Methoxybenzyl MPM OS•Op-Methoxyphenylsufonyl OMps OS•HPDimethylthiophosphinyl SMpt mRNA Messenger RNA OS•Methanesulfonyl or mesyl OMs MS Mass spectrometry OHOOSMethanesulfonic acid MSA SCH•2O4-(Methylsulfinyl)benzyl Msib OC•OS4-Methylsulfinylbenzyloxycarbonyl OMsz OOS•OOO2,4,6-Trimethoxybenzenesufonyl Mtb OS•OO2,3,5,6-Tetramethyl-4-methoxybenzenesulfonyl Mte OOCH• 4-Methoxytetrahydropyranyl MTHP SMTM CH•Methylthiomethyl 2 OS•C4-(methylthiomethoxy)butyryl OMTMB SO•CMTMECO 2-(Methylthiomethoxy)ethoxycarbonyl OO •O OS 2-(Methylthiomethoxymethyl)benzoxy MTMT C•OOS4-Methylthiophenoxycarbonyl Mtpc OS•OO2,3,6-Trimethyl-4-methoxybenzenesulfonyl Mtr OSOS•OO2,3,6-Trimethylbenzenesulfonyl(mesitylenesulfonyl) Mts m/z Mass to charge ratio (in MS) n nao NAD Nicotinamide adenine dinucleotide NADH Reduced NAD OBrNNBA HN-Bromoacetamide O BrN ON-Bromosuccinimide NBS O ClN ON-Chlorosuccinimide NCS Ni(acac)2 Nickel acetylacetonate O IN ON-Iodosuccinimide NIS Ni? Raney Nickel NON-Methyl morpholine NMM NMR Nuclear magnetic resonance O+N-OOOC•Noc 4-Nitrocinnamyloxycarbonyl NOE Nuclear Overhauser effect NOESY Nuclear Overhauser effect spectroscopy S•O+N- 2-Nitrophenylsulfenyl ONPS S•NO+N-3-Nitro-2-pyridinesulfenyl ONpys Nu Nucleophile OD Optical density CH•2O+N-o-Nitrobenzyl OONB ORD Optical rotary dispersion ot Oven temperature O-+ONK+-KNOPotassium azodicarboxylate OPADA O-O+NHCrOClPCC Pyridinium chlorochromate O+ONHCrO--OO+CrNHOOPyridinium dichromate PDC PdClCl PP Dichlorobis[tris(2-methylphenyl)phosphine]palladium PdCl2(tpp)2 O PdOPdOPd2(dba)3 Tris(dibenzylideneacetone)dipalladium PE Photoelectron +HP•C3Peoc O2-Phosphonioethoxycarbonyl or 2-(Triphenylphosphonio)ethoxycarbonyl O •H2C N2-(2’-Pyridyl)ethyl Pet PG Protective group CH•Phenyl Ph φ Phen NN1,10-Phenanthroline OC•OO 4-Methoxyphenacyloxycarbonyl OPhenoc Phth OOC••CPhthaloyl Pixyl 9-(9-Phenyl)xanthenyl OCH•2p-Methoxybenzyl PMB •H2COOp-Methoxybenzoxymethyl PMBM OS•OO2,2,5,7,8-Pentamethylchroman-6-sulfonyl Pmc OS•OPentamethylbenzenesulfonyl Pme OS•Op-Methylbenzylsulfonyl PMS -OO+C•Np-Nitrobenzoyl OPNB O-OOO+OSN+NSOOO-OOp-Nitrobenzenesulfonyl peroxide PNBSP OPOM 4-Pentenyloxymethyl or Pivaloxymethyl •H2CPPA Polyphosphoric acid (多聚磷酸) PPE Polyphosphate ester (聚磷酸酯) ppm Parts per mollion Ppoc 2-Triphenylphosphonioisopropoxycarbonyl S Pyridinium p-to;uenesulfonate Pr Propyl i-Pr Isopropyl OOOCS•O2-(Phenylsulfonyl)ethoxycarbonyl Psec •H2CSPhenylthiomethyl PTM PTC Phase-transfer catalysis •COPivaloyl Pv N Pyridine Py Pyoc 2-(2’- and 4’-pyridyl)ethoxycarbonyl q Quartet Rf Retention factor rRNA Ribosomal RNA rt Room temperature s Singlet or second O SOHScm S-Carboxymethylsulfenyl H• OSMethoxycarbonylsulfenyl chloride ClOScmCl SEM Trimethylsilylmeyhoxyethyl SES β-Trimethylsilylethanesulfonyl SET Single electron transfer •HCOSi(Phenyldimethylsilyl)methoxymethyl SMOM SN1 Unimolecular nucleophilic substitution SN2 Bimolecular nucleophilic substitution SN ’ Nucleophilic substitution with allylic rearrangement Snm S-(N’-Methyl-N’-phenylcarbamoyl)sulfenyl SiHN3SiH3 1,1,4,4-Tetramethyldisilyl azacyclopentane STABASE ONOSu Succinimidyl • t Triplet HNCH•2 OTrimethylacetamidomethyl Tacm +N-FTBAF Tetrabutylammonium fluoride +N-ITBAI Tetrabutylammonium iodide •Si TBDMS t-Butyldimethylsilyl Si• t-Butyldiphenylsilyl TBDPS O:SiOOSi:OO Tetra-t-butoxydisiloxane-1,3-diylidene TBDS OOH t-Butyl hydroperoxide TBHP Si•TBMPS Ot-Butylmethoxyphenylsilyl SiHTBS Tributylsilane SiCl Tert-butyldimethylsilyl chloride TBSCl O C• O O 4,4’-4”-Tris(benzyloxy)triphenylmethyl TBTr •CClOOClTcBoc Cl1,1-Dimethyl-2,2,2-trichloroethoxycarbonyl N NN Tetracyanoethylene NTCNE NN7,7,8,8-Tetracyanoquinodimethane NN TCNQ Tcroc 2-(Trifluoromethyl)-6-chromonylmethylene carbonyl OFFCH:OF2-(Trifluoromethyl)-6-chromonylmethylene Tcrom Si•TDS Thexyl dimethylsilyl NTEA Triethylamine +N-BrTetraethylammonium bromide TEAB -Cl+NTEBAC Benzyltriethylammonium chloride Tebbs’ Tebbs’ CH2CH2 NCH2CHN2 CH2CHTEDA Triethylene diamine 2 Si•COO 2-(Trimethylsilyl)ethoxycarbonyl Teoc Si•TES Triethylsilyl OOS• FFTrifluoromethanesulfonyl FTf HOO FFTrifluoroacetic acid FTFA HOO FFTrifluoroacetic acid FTFAA FFFOSOOHTrifluoromethanesulfonic acid TfOH C• Thexyl 2,3-Dimethyl-2-butyl O Tetrahydrofuran THF O Tetrahydropyran THP TIPDS 1,3-(1,13,3-Tetraisopropyldisiloxanyllidene) Si• Triisopropylsilyl TIPS OO O C•OOOOO4,4’,4”-Tris(levulinoxy)triphenylmethyl OTLTr NNTMEDA N,N,N’,N’-Tetramethylethylene diamine NNHN1,1,3,3-Tetramethylguanidine TMG TMP 2,26,6-Tetramethyl piperidine OOC•OTMPM Trimethoxyphenylmethyl SiSi• Trimethylsilyl or Tetramethylsilane TMS Si•COO2-(Trimethylsilyl)ethoxycarbonyl TMSEC O OC• OTri(p-methoxyphenyl)methyl TMTr Tol Tolyl Torr 1 mmHg OS•p-Toluenesulfonyl OTos TPAP Tetrapropylammonium perruthanate (Pr)4NRuO4 TPP Tetraphenylporphine OS•O Triisopropylbenzenesulfonyl TPS Si• Triphenylsilyl TPS tR Retention time C• Trityl (triphenylmethyl) Tr Trityl -OH+NTriton B Benzyltrimethylammonium hydroxide Tritylone 9-(9-Phenyl-10-oxo)anthryl ClClC•OCl2,2,2-Trichloroethoxycarbonyl OTroc OS•p-Toluenesulfonyl or Tosyl OTs TS Transition state OSOHTSA Op-Toluenesulfonic acid OCH•2STse O2-(p-Toluenesulfonyl)ethyl OSOHTsOH Op-Toluenesulfonic acid TyrOH Tyrosine UV Ultraviolet Voc Vinyloxycarbonyl Z Benzyloxycarbonyl