金属有机骨架材料MOFs及其应用

null金属有机骨架材料及其应用金属有机骨架材料及其应用研究背景研究背景早在20世纪90年代中期，第一类MOFs就被合成出来，但其孔隙率和化学稳定性都不高 目前，已经有大量的金属有机骨架材料被合成，这些金属有机骨架中多数都具有高的孔隙率和好的化学稳定性 nullOmar M. Yaghi received his Ph.D. from the University of Illinois-Urbana (1990) with Professor Walter G. Klemperer. He was an NSF Postdoctoral Fellow at Harvard University (1990-92) with Professor Richard H. Holm. He has been on the faculties of Arizona State University (1992-98) and University of Michigan (1999-2006). His current position is the Jean Stone Professor of Chemistry at UCLA. nullMOFs合成方法特点应用分类Design and synthesis of an exceptionally stable and highly porous metal-organic frameworkDesign and synthesis of an exceptionally stable and highly porous metal-organic frameworkThis synthesis is achieved by borrowing ideas from metal carboxylate cluster chemistry, where an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxylates.Li, H. Eddaoudi, M. O'Keeffe, M. Yaghi, O. M. Nature 402, 276-279 (1999) MOF-5一个空腔的结构图MOF-5一个空腔的结构图MOF-5的层结构图MOF-5的层结构图MOF-5的吸附性能MOF-5的吸附性能Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large PoresInterwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large PoresChen, B. L. Eddaoudi, M. Hyde, S. T. O'Keeffe, M. Yaghi, O. M. science 291, 1021-1023 (2001) nullChen, B. L. Eddaoudi, M. Hyde, S. T. O'Keeffe, M. Yaghi, O. M. science 291, 1021-1023 (2001) Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane StorageSystematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane StorageEddaoudi, M. Kim, J. Rosi, N. Vodak, D. O'Keeffe, M. Yaghi, O. M. science 295, 469-472 (2002) nullnullHydrogen Storage in Microporous Metal-Organic FrameworksHydrogen Storage in Microporous Metal-Organic FrameworksRosi, N. L. Eckert, J. Eddaoudi, M. O'Keeffe, M.Yaghi, O. M. science 300, 1027-1029 (2003) MOF-5的储氢性能MOF-5的储氢性能78K298KnullRowsell, J. L. C. Spencer, E. C. Eckert, J. Yaghi, O. M. science 309, 1350-1354 (2005) Metal Organic Frameworks as Adsorbents for Trapping and Preconcentration of Organic PhosphonatesMetal Organic Frameworks as Adsorbents for Trapping and Preconcentration of Organic PhosphonatesNi, Z. Jerrell, J. P. Cadwallader, K. R. Masel, R. I. Analytical Chemistry 79, 1290-1293 (2007) In this paper, IRMOF1 is tested as an adsor-bent for preconcentration for the first time using dimethyl meth-ylphosphonate (DMMP) as a test case. null实验流程图实验流程图吸附性能吸附性能富集效果富集效果Metal–Organic Framework MIL-101 for High-Resolution Gas-Chromatographic Separation of Xylene Isomers and EthylbenzeneMetal–Organic Framework MIL-101 for High-Resolution Gas-Chromatographic Separation of Xylene Isomers and EthylbenzeneGu, Z. Y. Yan, X. P. Angewandte Chemie-International Edition 49, 1477-1480 (2010) We show the first fabrication of the MOF- coated capillary column for high-resolution GC separation. we choose MIL-101 as the stationary phase and xylene isomers and ethy-lbenzene (EB) as the targets for separation.分离效果分离效果影响因素影响因素抗干扰能力抗干扰能力null