阴离子沥青乳化剂产品说明

阴离子沥青乳化剂产品 阴离子沥青乳化剂kzw-803Y 性能及应用 kzw-803Y是一种阴离子慢裂慢凝型沥青乳化剂～适用于喷洒、拌合型乳化沥青的制备～广泛应用于透层油、下封层等施工中。 主要技术指标 外 观,25?, 无色透明液体 含 量 ?30% PH值,1%水溶液, 9.0-11.0 溶解性 易溶于水 典型配方,重量, 沥青～% 50 kzw-803Y～% 0.8-1.2 水～% 50 kzw-803Y应加入温水中搅拌溶解～然后用氢氧化钠水溶液,15%,调节PH至12～调碱过程建议使用pH计 注:乳化过程需注意用阴离子水溶液充分清洗机器～防止阴阳离子接触后影响乳化剂的乳化能力进而影响乳化沥青的状态。 储存及运输 kzw-803Y通常储存在阴凉、通风干燥的库房内～贮存期为两年以上。 包装:聚乙烯塑料桶包装 净重50kg/桶 聚乙烯塑料桶包装 净重200kg/桶 阴离子沥青乳化剂,磺酸盐型, loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: 磺酸盐型阴离子乳化剂是直链烷烃、烷基苯、烷基萘等与硫酸或发烟硫酸经磺化和碱中和而制成的面活性剂～其化学式为:R-SO3Na R为碳原子数为8-20中间的碳链。 在沥青乳化剂中常用的磺酸盐型乳化剂只要有烷基苯磺酸盐、烷基磺酸盐和植物油磺酸盐。 ,一, 烷基苯磺酸盐 烷基苯磺酸盐又称石油苯磺酸盐～这是因为所用原料烷基和烯烃是由天然或人造石油的馏分制的。其分子式为:R,SO3M R为CnH2n+1的长链烷基～以C10-C18应用最多, M为金属离子Na、K～以Na应用最多。 从烷基苯磺酸钠分子中可以看出～是由烷基苯磺化～直接引入磺酸基经碱中和而成。其他亲油基,或称憎水剂、疏水基,为烷基苯,C12H2n，1,C6H4,,亲水基为磺酸盐。在个烷基苯链细长,链长为13-20Å,直径小于4.9Å,。由于合成与原料的不同烷基链的链长及支链情况不同～苯环和烷基连接位置不同～以及磺酸基引入苯环的多少和位置不同等～烷基苯磺酸钠不是单一成分～而是一个复杂的含异构体的体系。 在支链烷基苯磺酸盐中～表面张力以14碳最低～12碳次之～以直链18个碳乳化能力强。各种不同异构体的C12～以n=12为最好。苯核在烷基链上结合位置～以苯环移向中心的为好～以3-苯基异构体的最好。 烷基苯磺酸钠与羧酸盐相比～磺酸盐不易与酸及金属离子反应～可在loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: 宽的PH值范围内及相当的金属离子浓度下保持活性。简单的苯基磺酸盐没有太大的表面活性～其核上有一个或几个短链的烷基取代基对界面活性就有不同程度的提高～取代的烷基使阴离子的非极性部分的憎水性增大。 烷基苯磺酸钠为白色或淡黄色粉末或片状固体～对酸、碱或硬水都比较稳定～但在240?时极易发生分解～表面张力为0.3Mn/cm。 十二烷基苯磺酸钠、双十二烷基苯基醚二磺酸钠是乳化沥青中常用的阴离子乳化剂。用平均分子量400-500单烷基和双烷基苯磺酸钠～可制得贮存稳定性好的沥青乳液。如果与凝结剂,如氯化钙或水泥,混合～可控制其分裂速度。与其他某些阴离子乳化剂混合使用时～所发挥的乳化效果比单独使用时～其乳化效果更好～具有选择性的协同效应～也是乳化沥青中常用的阴离子乳化剂。 在苯环上的烷基碳原子很少～甚至为零时,或仅有两个甲基,～如苯磺酸钠、甲基磺酸钠、二甲基苯磺酸钠和异丙磺酸钠～能增大烷基苯磺酸钠及其他组分在水溶液中的溶解度～常作表面活性剂的助溶剂。 ,二, 烷基磺酸钠 烷基磺酸钠又称为石油磺酸钠～俗称石油皂。它是由高沸点石油馏分,230?-320?,先行氢化或用浓硫酸处理除去不饱和烃而得到的纯烷基～在紫外光照射下与氯和二氧化硫作用生成一氯化合物～再用烧碱皂化而成。其化学式为:R,SO3Na R为C13-C18的烷基或烷基苯稠环结构。 烷基磺酸钠的表面活性与烷基苯磺酸钠接近～它在碱性、中性和弱酸loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: 性溶液中较为稳定～在硬水中仍具有较好的乳化能力。支链烷基苯磺酸钠溶液的溶解度及临界胶束浓度、表面张力和碳原子数有关～乳化能力以C15-C16为好。 烷基磺酸钠为或淡黄色粉末～易溶于水～是乳化沥青中常用的乳化剂。该产品有效物为28?1%～不皂化物,以100%有效物计,?6%～1%水溶液PH值为7-8～NaCl含量小于6%。 ,三, 拉开粉 拉开粉的学名为二丁基萘磺酸钠～属于烷基萘基磺酸盐中的一种。由醇、萘与发烟硫酸作用后即可得二丁基萘磺酸～再经烧碱处理而制得萘磺酸盐表面活性剂～拉开粉为俗名。其化学结构式为:CH2CH2CH2CH3 NaO3S CH2CH2CH2CH3 拉开粉为白色或微黄色粉末～液体呈浅橙色透明液体～易溶于水。固状物加热至100?不熔化而磺化～并逸出碱性气体～对酸碱和硬水都稳定～活性物含量为60?1%,PH值为7-8. 将两个烷基化的萘磺酸盐用亚烷基连接起来得到的化合物具有较大的分散效果～是良好的分散剂。例如～亚甲基二异丙基萘磺酸钠、亚甲基二异丙基萘磺酸钾等。 ,四, 木质素磺酸盐 木质素磺酸盐又称磺化木质素。木质素是愈疮木基,4-羟基-3-甲氧基苯基,的多聚物～是从造纸工业废液中提取的沥青乳化剂～其基本化学结构单元为: α β γ loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: HO-CH=CH-CH2OH(OCH3)1-2 在α-碳原子上引入磺酸基～则成为磺酸盐～它是由亚硫酸盐制浆废液经石灰乳沉淀酸溶～转化而制得的。其分子式为: SO3NaHO-C=CH-CH2OH(OCH3)1-2 针叶树含一个甲氧基～阔叶树含有两个甲氧基～侧链双键发生加合反应。最普通的磺酸盐相对分子量约为4000.一般来说低分子量木质素磺酸盐多为直链～在水溶液中缔合在一起,高分子量木质素磺酸盐多为支链～在水溶液中显示出聚合电解质行为～并且高分子量部分很难生物降解。 木质素磺酸盐呈黄色固体～有良好的分散性～是固体在介质中的较好分散剂。通常用来制造慢裂型乳化沥青。 此外～磺化妥尔油皂、磺化琥珀酸、α-烯烃磺酸盐、磺化松香、磺化棉籽油等～都可用作阴离子乳化沥青的乳化剂～有的还可改善沥青对矿物集料的粘附性。 阴离子沥青乳化剂,羧酸盐型, 羧酸盐型乳化剂～它是由大分子链的羧酸与碱作用而生成的阴离子沥青乳化剂。常用的有脂肪酸盐和环烷酸盐。其化学结构为:RCOOM R为憎水烃基～为长烃脂肪烃或环烷烃基～碳原子个数为9-21. M为金属离子～包括K+ Na+ 在羧酸盐型沥青乳化剂中应用最多的为油酸钠、松香酸钠、月桂酸钠、环烷酸钠等。脂肪酸的碳链越长～亲油性越强～凝固点越高～制成的脂肪酸皂越硬～在水中的溶解性越差。脂肪酸的碳链越短在水中的溶loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: 解性越好～亲油性越差～对沥青的乳化效果越差。选择脂肪酸盐乳化剂一般选择碳数为12-20之间～其中应用最多的碳原子为12-18. 烷酸存在于很多沥青中～可以从沥青中提取。用作沥青乳化剂的环烷酸的酸值应在75-175之间～沥青酸值在0.75KOH/g左右或更高的环烷酸沥青～可简单的用碱性乳化剂所乳化～可获得较满意的环烷皂乳化沥青。 ,一, 油酸皂 油酸皂是用天然油脂与氢氧化钠进行化学反应而生成的一种阴离子型乳化剂～学名为顺-9-十八碳烯酸盐～是含一个双键的不饱和脂肪皂。其化学式为: CH3(CH2)7-CH=CH-(CH2)7COONa 油酸是橄榄油、牛脂的主要成分～碳数均为18～由于分子中含有双键～增加了亲水性～在水中溶解性增强～具有极强的表面活性～是乳化沥青中常用的沥青乳化剂。但在硬水中与铝、镁等离子形成不溶性的铝皂、镁皂～影响乳化效果。 ,二,硬脂酸钠 硬脂酸钠是由硬脂酸和碱作用而生成的硬脂酸皂。其化学式为CH3(CH2)16Na 硬脂酸钠多数是含有十八碳的饱和脂肪酸皂。其碳链越长～憎水性越强～亲水性羧酸基仅为一个～亲水性不足～顾在冷水中溶解性较差～易溶于热水。但对沥青亲和力较大～是沥青较好的乳化剂。 油酸皂虽与硬脂酸皂的碳链基本相等～均为18个碳组成～但因含有loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: 双键～其性质很不相同。由于受双键的影响～亲水性较好～易溶于水～对沥青的乳化能力较硬脂酸皂好。 ,三, 月桂酸皂 月桂酸皂是月桂酸油脂与氢氧化钠作用而生成的一种阴离子乳化剂。其化学式为 C11H23COONa 月桂酸脂主要存在于椰子油中～由于碳数为12～疏水基较短～易溶于水～同样是沥青乳化中较好的乳化剂。 ,四, 松香油皂 松香油皂是天然松香和碱作用而生成的一种阴离子乳化剂。其化学式为C19H29COONa。 松香是从切开针叶树干渗出的粘稠性树脂类物质～在室温下呈半透明状态～主要成分是松香酸和松香酸酐～为不饱和化合物～活性较大～易于造化～形成松香酸皂。在每个松香酸皂分子中含有两个不饱和双键～由于双键的存在可增强对水的亲和力～但影响沥青的乳化性能～通常是加氢除去双键。 松香皂易溶于水～有较好的水溶性和抗硬水能力～润湿能力较好～为沥青常用的阴离子乳化剂。 loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: loan management (post) review: 1, approval criteria have been implemented; 2, the contract is correct; 3, in line with the contract, payment; 4, no other major cases against loan security;、Reviewed by: date of record form 9: qilu bank borrowing by single years of maximum amount a maximum no-loan borrowers: borrowers: ... Borrower name number, line of credit expiry date year month day to year month day maximum number of years in the loan contract are the top line opened, the borrowed and requested your bank opened credit lines above, is hereby requested. Borrower signature: date agreed to open credit lines. Customer Manager signature: date agreed to open credit lines. Loan review signature: date line cancellation-I did not use the loan amount, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: date case, agree to write off loans. Loan review signature: date of record form 16: qilu self credit for credit card cancellation application form name of borrower ID number and credit limit expiration date year month day to year month day year contract number self-service card-I do not use credit, your bank credit lines to be cancelled. -Credit loan principal repayment, your bank credit lines to be cancelled. Borrower signature: date-unused credit lines, agree to write off loans. -Credit loan principal repayment, agree to write off loans. Customer Manager signature: